You made an arithmatic error.
If the green LED is a very bright modern 3.4V one then it has the same chemistry as a white and blue LED. If the green LED is a dimmer old one then it is about 2.2V.
Why 14V? In a car?
(14V - 3.4V)/3M= 3.4uA, not 3.4pA. Maybe your 3M resistor is actually only 30k ohms?