Hi Kevin
In a pn junction in equilibrum, where p and n regions "touch", majority carriers from each region recombine with majority carriers from the other region. That is: free electrons from the n region recombine with holes in the p region and holes from the p region recombine with free electrons in the n region. A depletion region is thus created. In the depletion region there are no "mobile" carriers. The diffused holes leave behind uncovered fixed negative charges and similarly there are fixed positive charges left behind by the diffused electons. In this way, a separation of charges occurs, causing an electric field (- is in the p region and + in the n region). This electic field is called built-in potential and has the opposite polarity of the battery when you forward bias the junction. It is given by:
Vbi=VTln[(NdNa)/ni2 ]
where:
Vbi is the built-in voltage
VT is the thermal voltage for Si (26mV/deg C)
Nd and Na is the concentration of doping atoms in the n and p region respectively
ni is the intrinsic carrier concentration in Si
This potential is constant, has a value of 0,7V approximately for Si diodes and normal doping (depends on doping and temperature), and you have to overcome it in order to have a current flow through the junction. This is practically what you measure and call forward voltage drop. When you bias the diode you do have an electron current and practically you create an electric field opposite to the built-in voltage. When the electric field you apply equals or exceeds the built-in voltage, your diode conducts.