You could rewind the secondary 5Volts (or 3.3V) in a computer PSU to 2Volts (or which voltage you want) and boost the rectifier circuit. You have to arrange a shunt and some feedback to the regulator circuit to obtain a constant current.
There are different ways to do this but these are heavier and more expensive.
But 1 micro ohm and 100A gives you .1mV. You said you have a mV meter.
Seems like a better meter would be an "easier road", than the cost and trouble of constructing a 100A source (these current levels are not easy to deal with). Contact resistance and wire IR drop come into consideration REALLY FAST!!
I agree, 100A is not easy to handle and there might be a better solution to this depending on the target for the measurements. This amount of current will sure require some heavy duty KELVIN CLIPS! ;D