Yes, I did not describe the wire diameter in a clear way. Harald is better at english than most native speakers.
Interestingly, car starter connectors are always known as cables not wires.
I think that the insulation of the wiring of cars or combine harvesters has to not only provide isolation but also to withstand vibration, a robust covering is then necesary. Flexible mains cables have a secondary insulation covering. In the past single insulated twin bell wire was adequate.
Recently, I have been winding a coil using wire, not cable even though it has insulation on it.
Edit:
I just had a look at the thread title, it is "Voltage rating of wire"