The picture is a simple battery connected across two resistors in series, as you describe.
The first thing to understand is that the current is the same everywhere in the loop. There's nowhere for current to leave the circuit, so the current is the same at every point around it. I've labelled it I.
The second thing to know is that the total resistance of the two resistors in series is the sum of their individual resitances. That is, R1 + R2.
We can use Ohm's law to find out I. Since we know the battery's voltage, and we know the total resistance that this battery is pushing current through, we can work out the current I through those resistances:
I = Vs / (R1 + R2)
Now that we know the current I, we can work out what voltages will appear across the two resistances, again with Ohm's law:
VR1 = I * R1
VR2 = I * R2
Play with some numbers: Let's say Vs (battery voltage) is 9V, R1 = 1kOhm and R2 = 2kOhm.
I = 9V / (1000 + 2000) = 3mA
VR1 = 3mA * 1000 = 3V
VR2 = 3mA * 2000 = 6V
The sum of the two voltages across the resistors VR1 + VR2 (that you can measure to prove this empirically) will always be 9V, regardless of the resitances used.
In other words, the resistances can be chosen to divide the voltage across them into two separate voltages whose sum is 9V. The ratio of those two voltages is the ratio of the resistances. Thus, to divide your 9V by exactly 2 (to create 4.5V and 4.5V), choose two resistors of the same value.
You can use as many resistances in series as you like, to divide a voltage into any number of smaller voltages.
The maths above reduces to this:
VR1 = Vs * R1 / (R1 + R2)
VR2 = Vs * R2 / (R1 + R2)
Note that you don't need to know the current at all, but understanding the principle of the current being the same through both resistances allows you to see how the resistances each develop a share of the total voltage across them.
One last observation; if you are thinking you can now power a small 3V lamp by connecting it across the 1kOhm resistor in our example, think again. The lamp's low low resistance (just a few Ohms) in parallel with R1 will change the whole scenario.
View attachment 39618