For driving white LEDs from a lower voltage than Vf there are chips from Maxim, Microchip, and (probably) National. You'll have to do a parametric search for them.
http://www.maxim-ic.com/index.cfm
http://www.microchip.com/1010/index.htm
http://www.national.com/
There are also discrete component circuits for them. These have several topologies, each suited to specific needs.
http://elm-chan.org/works/led2/report.html
http://members.shaw.ca/novotill/LedSupplyRegAA/index.htm
http://www.satcure-focus.com/hobby/page2.htm
http://www.elektor-electronics.co.uk/miniproj/download/010130uk.pdf
The first three are variations on a blocking oscillator. The last one is different- it does not require a tapped inductor, but does need two transistors.